If 2.50 mL of vinegar requires 34.90 mL of 0.0960 M NaOH to reach the equivalenc
ID: 503998 • Letter: I
Question
If 2.50 mL of vinegar requires 34.90 mL of 0.0960 M NaOH to reach the equivalence point in a titration, how many grams of acetic acid are in 500.0 mL of this vinegar? [density of vinegar = 1.01 g mL^-1] Calculate the mass % of acetic acid in the vinegar in the previous exercise (question#1 above). Assume that the density of the vinegar is 1.01 g mL^-1. If phenolphthalein is used as indicator, what color will the solution be at the endpoint? In your reading, it talks about errors that are possible when doing titrations, what are three of those possible sources of error?Explanation / Answer
Q1.
V = 2.5 mL of vinegar
V = 34.90 mL of M = 0.096 M of NaOH
find mass of acetic acid in V = 500 mL if D = 1.01 g/mL
so...
first, find mol of base
mmol of base = MV = 0.0960*34.90 = 3.3504 mmol of NAOH
ratio is 1:1
so
1 mol of acid = 1 mol f base
3.3504 mmol of base = 3.3504 mmol of acid
mass = mol*MW = (3.3504*10^-3)(60.05 ) = 0.201191 g of acetic acid
this was in 2,50 mL of sample
so
in 500 mL --> 500/2.5 * 0.201191 = 40.2382 g of acetic acid
Q2.
if we need mass, we need to chagne vineger to mass
mass of vinegar in 500 mL = D*V = 1.01*500 = 505 g of vinegar
% mass = 40.2382 /505* 100 = 7.96796 %
Q3.
The color will start as transparent, since it is acidic, evnetually, when pH = 8-9 approx, the color changes to pink/purple
Q4.
1 - incorrect indicator
2 - excess titrant addition
3 - incorrect meassurement of volumes (ignoring miniscus, etc..)
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