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For the reactions shown below, we added 5.00 mL of 0.0370 M NaOH to a test tube

ID: 568007 • Letter: F

Question

For the reactions shown below, we added 5.00 mL of 0.0370 M NaOH to a test tube containing one of the two cations (Ni2+ or Fe3+) and recovered 0.00659 g of precipitate.

Ni(NO3)2(aq) + 2 NaOH(aq) Ni(OH)2(s) + 2 NaNO3(aq)
Fe(NO3)3(aq) + 3 NaOH(aq) Fe(OH)3(s) + 3 NaNO3(aq)

How much precipitate in moles would be recovered theoretically if the ion was Ni2+? (Enter an unrounded value. Use at least one more digit than given.)

How much precipitate in grams would be recovered theoretically if the ion was Ni2+?

How much precipitate in grams would be recovered theoretically if the ion was Fe3+?

Explanation / Answer

nO of mol of NnaOH used = M*V

                       = 0.037*5

                       = 0.185 mol

1 mol Ni(OH)2(s) = 2 mol NaOH(aq)

No of mol of Ni(OH)2(s) = 0.185/2 = 0.0925 mol

Amount of Ni(OH)2(s) = 0.0925*92.708 = 8.57 g


1 mol Fe(OH)3(s) = 3 mol NaOH(aq)

No of mol of Fe(OH)3(s) = 0.185/3 = 0.06167 mol

Amount of Fe(OH)3(s) = = 0.06167*88.86 = 5.5 g

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