1a. Which method will not make a ketone? 1-propanol + PCC 2-methylpropene + O3 p
ID: 962517 • Letter: 1
Question
1a. Which method will not make a ketone?
1-propanol + PCC
2-methylpropene + O3
propyne + H2SO4/HgSO4
1b. The carbonyl carbon in acetone is a ___ than ____. It reacts with a _____ to form a ____ intermediate.
better nucleophile
poorer nucleophile
better electrophile
poorer electrophile
OH-
H2SO4
nucleophile
electrophile
trigonal planar
tetrahedral
trigonal bipyramid
1c. 1 equivalent of ROH reacts with acetone with a ____ catalyst to form a ____.
acid/hemiacetal
base/hydrate
acid/acetal
1d. Acetone reacts with methyl amine to form a:
hydrate
imine
eneamine
Explanation / Answer
1a. Which method will not make a ketone?
solution :- 1-propanol + PCC will not make ketone because primary alcohol forms aldehyde on oxidation.
2-methylpropene + O3 = will make ketone
propyne + H2SO4/HgSO4 = will make ketone
1b. The carbonyl carbon in acetone is a ___ than ____. It reacts with a _____ to form a ____ intermediate.
solution :-
Part 1 = poorer electrophile
Part 2 = OH- to form tetrahedral
1c. 1 equivalent of ROH reacts with acetone with a ____ catalyst to form a ____.
solution :- when acetone reacts with ROH then it forms acid /hemiacetal
1d. Acetone reacts with methyl amine to form a:
Solution :-
When the acetone react with methyl amine then it removes the water molecule and forms C=N bond which is called as imine
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