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8) A chemical equilibrium that is a classic example of a statistical derivation

ID: 882857 • Letter: 8

Question

8) A chemical equilibrium that is a classic example of a statistical derivation of thermodynamic reaction properties is the gas phase dissociation of iodine: I (g) 21 a) Calculate the thermal wavelengths for 12 and I at T-298K. b) Using the data in the table above calculate the rotational and vibrational partition functions of at T-298K. c) Calculate the translational partition functions for I and I2. Assume V 0.0244 m3 and T 298K. d) Using your results from parts a-c, calculate the overall partition functions for I and at T-298K. including the contributions from electronic motions. Express your answers in scientific notation and remember that De is in kJ per mole units. The ground state degeneracy for I is gu 34 e) Using your results from part d, calculate the equilibrium constant KP for the gas phase dissociation of I2. Assume N NA. f) Using your result from part e, calculate the standard free energy change for the gas phase dissociation of I2 at T-298K.. Is the dissociation of I2 energetically favorable at T 298K? g) How good is this statistical calculation? Tables of thermodynamic data for inorganic compounds at T 298K give for I (g) AG (I) 70.2k.Umol and for (g) AG (12)S19.3k mol 1. Using these data calculate AGO for the gas phase

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