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calorimetry lab Trial 1 Trial 2 Trial 3 Trial 4 initial temp NaOH 22.3 C 23.1 22

ID: 881818 • Letter: C

Question

calorimetry lab

                Trial 1                                   Trial 2           Trial 3           Trial 4

initial temp NaOH 22.3 C             23.1              22.0                22.1

        initial temp acid      22.0 c            23.0              22.5                 22.7

        final temp              38.2 C            36.0               37.7                 39.0

        delta T                  15.09              12.9               15.7                 16.9

         mass of solution 76.021g         76.021              75                   78

moles of limiting reagent    0.098        0.09                 0.09               0.096

Find

1, Delta H

2, Average delta H

3, Standard divation delta H

4 % erroe delta H

Explanation / Answer

Trial-1

First let us calculate the heat (Q) for the reaction

The amount of heat released corresponds to:

q = (76.021 g)(4.184 J/g*C)(38.2 - 22.0 C) = 5152.76 J

Since the reaction takes place in a calorimeter, one can assume pressure is constant. Under these conditions one can also assume the Q of the reaction = the change in enthalpy (Delta H)
Hence for 0.098 moles Delta H = 5152.76 x 0.098 = 504.97 J

Delta H1 = = 504.97 J

Trial-2

Similarly, if calculated

q = (76.021 g)(4.184 J/g*C)(36 - 23 C) = 4134.93 J

For 0.09 moles Delta H = 4134.93 x 0.09 = 372.14 J

Delta H2 = = 372.14 J

Trial-3

q = (75 g)(4.184 J/g*C)(37.7 - 22.5 C) = 4769.76 J

For 0.09 moles Delta H = 4769.76 x 0.09 = 429.27 J

Delta H3 = = 429.27 J

Trial-4

q = (78 g)(4.184 J/g*C)(39 - 22.7 C) = 5319.53 J

For 0.096 moles Delta H = 5319.53  x 0.096 = 510.67 J

Delta H4 = = 510.67 J

2) Average delta H : (504.97 J + 372.14 J+ 429.27 J + 510.67 J)/4

                                   = 454.26 J

3, Standard divation delta H : 66.13

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