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Nitrogen dioxide reacts with water to produce oxygen and ammonia: 4NO2(g)+6H2O(g

ID: 707223 • Letter: N

Question

Nitrogen dioxide reacts with water to produce oxygen and ammonia: 4NO2(g)+6H2O(g)?7O2(g)+4NH3(g)

How many grams of NH3 can be produced when 3.80 L of NO2 reacts at 415 ?C and 735 mmHg ?

Express your answer with the appropriate units.

A sample of methane (CH4) has a volume of 26 mL at a pressure of 0.87 atm . What is the final volume, in milliliters, of the gas at each of the following pressures, if there is no change in temperature and amount of gas?

0.20 atm

2.30 atm

2500 mmHg

65.0 torr

Express your answer using two significant figures!!!!

Explanation / Answer

4NO2(g)+6H2O(g)-------------->7O2(g)+4NH3(g)

P   = 735mmHg

      = 735/760   = 0.967 atm

V    = 3.8L

T     = 415+273   = 688K

PV      = nRT

n      = PV/RT

          = 0.967*3.8/0.0821*688   = 0.065moles

4NO2(g)+6H2O(g)-------------->7O2(g)+4NH3(g)

4 moles of NO2 react with H2O to gives 4 moles of NH3

0.065 moles of NO2 react with H2O to gives = 4*0.065/4   = 0.065 moles of NH3

mass of NH3   = no of moles * gram molar mass

                         = 0.065*17   = 1.105g

initial                                                    Final

P1 = 0.87atm                                    P2 = 0.2atm

V1   = 26ml                                        V2   =

       P1V1      =    P2V2

           V2         = P1V1/P2

                        = 0.87*26/0.2   = 113ml

initial                                                    Final

P1 = 0.87atm                                    P2 = 2.3atm

V1   = 26ml                                        V2   =

       P1V1      =    P2V2

           V2         = P1V1/P2

                        = 0.87*26/2.3 =9.8ml

nitial                                                    Final

P1 = 0.87atm                                    P2 = 2500mmHg = 2500/760   = 3.29atm

V1   = 26ml                                        V2   =

       P1V1      =    P2V2

           V2         = P1V1/P2

                        = 0.87*26/3.29 6.9ml

nitial                                                    Final

P1 = 0.87atm                                    P2 = 65torr = 65/760   = 0.0855atm

V1   = 26ml                                        V2   =

       P1V1      =    P2V2

           V2         = P1V1/P2

                        = 0.87*26/0.0855 = 264.6ml

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