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Read each question and grading rubric thoroughly. Be sure to include units on nu

ID: 580688 • Letter: R

Question

Read each question and grading rubric thoroughly. Be sure to include units on numerical answers, to the correct number of significan t figures, where appropriate. 1. Consider the unbalanced equation below: L,os() FCo(8) )+) unbalanced (a) (2 pts) What element is being oxidized? OI OC oo O nothing (b) Balance the equation above using the half- reaction method in acidic conditions. Include state symbols! i. (6 pts) Balanced Oxidation half-reaction ii. (6 pts) Balanced Reduction half-reaction ili. (6 pts) Balanced overall equation for this reaction, simplified, based on your answers above. Show work Simplified: (c) (10 pts) If 10.53 g of 120s was allowed to react with 0.575 g of CO, how many grams of 120s would be leftover?

Explanation / Answer

Ans 1 :

a) C

Carbon is getting oxidised. Its oxidation state has been increased from +2 to +4.

b)

i) Balanced oxidation half reaction :

5CO + 5H2O = 5CO2 + 10H+ + 10e-

ii) Balanced reduction half reaction :

I2O5 + 10H+ + 10e- = I2 + 5H2O

iii) The balanced overall reaction is given as :

5CO + I2O5 + 5H2O + 10H+ + 10e- = 5CO2 + I2 + 5H2O + 10H+ + 10e-

Simplified :

5CO + I2O5 = I2 + 5CO2

c)

10.53 g of I2O5 = 10.53 / 333.8 = 0.032 moles

0.575 g of CO = 0.575 / 28.01 = 0.020 moles

0.032 moles of I2O5 will require 0.032 x 5 = 0.16 moles of CO , so CO is the limiting reagent

0.020 moles of CO will require 0.020 / 5 = 0.004 moles of I2O5

Mass of I2O5 utilised = 0.004 x 333.8 = 1.37 grams

So mass of I2O5 left unreacted = 10.53 - 1.37

= 9.16 grams

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