SO lost with this. Please help! Thank you so much. I really just don\'t even kno
ID: 3898782 • Letter: S
Question
SO lost with this. Please help! Thank you so much. I really just don't even know where to start.
Explanation / Answer
a)
Q - W = U2 - U1
We have Q = 0 and W = 0.
So U2 - U1 = 0
For cold gas, U2 - U1 = (0.6*m)*Cv*(Tc - Ti)
For hot gas, U2 - U1 = (0.4*m)*Cv*(Th - Ti)
Adding them, total U2 - U1 = m*Cv*[0.6*(Tc - Ti) + 0.4*(Th - Ti)]
Equating it to zero, m*Cv*[0.6*(Tc - Ti) + 0.4*(Th - Ti)] = 0
or 0.6*(Tc - Ti) + 0.4*(Th - Ti) = 0
Putting values for mode 1, 0.6*(-18 - 20) + 0.4*(70-20) = -2.8 which is non-zero.
Hence, mode 1 violates law of conservation of energy.
Putting values for mode 2, 0.6*(-18 - 20) + 0.4*(70-20) = -2.8 which is non-zero.
Hence, mode 2 violates law of conservation of energy.
b)
Q - W = du
Now, Q = Tds and W = p*dV
Hence, T ds = du + p*dV
Also, h = u + pv
dh = du + p*dv + v*dp
So, T ds = dh - v dp
ds = (dh / T) - (v/T)*dp
But dh / dT = Cp and pV = RT
So, ds = (Cp*dT / T) - (R/p) dp
Integration gives, s2 - s1 = Cp ln (T2 / T1) - R ln (p2 / p1)
Now, Cp = gamma*R / (gamma - 1)
So, s2 - s1 = (gamma*R / (gamma - 1)) ln (T2 / T1) - R ln (p2 / p1)
s2 - s1 = R*[(gamma / (gamma - 1)) * ln (T_f / T_i) - ln (P_f / P_i)]
For n moles,
S2 - S1 = nR*[(gamma / (gamma - 1)) * ln (T_f / T_i) - ln (P_f / P_i)]
c)
For mode 1:
For cold gas:
S2 - S1 = 0.6*8.314*[(1.4 / (1.4 - 1)) * ln ((-18 + 273) / (20+273) - ln (1 / 5)]
S2 - S1 = 6.603 J/K
For hot gas:
S2 - S1 = 0.4*8.314*[(1.4 / (1.4 - 1)) * ln ((70 + 273) / (20+273) - ln (1 / 5)]
S2 - S1 = 7.186 J/K
Net S2 - S1 = 7.186 + 6.603 = 13.789 J/K
Since S2 - S1 > 0, it does not violate 2nd law.
For mode 2:
For cold gas:
S2 - S1 = 0.6*8.314*[(1.4 / (1.4 - 1)) * ln ((-18 + 273) / (20+273) - ln (5 / 5)]
S2 - S1 = -2.425 J/K
For hot gas:
S2 - S1 = 0.4*8.314*[(1.4 / (1.4 - 1)) * ln ((70 + 273) / (20+273) - ln (5 / 5)]
S2 - S1 = 1.833 J/K
Net S2 - S1 =1.833 - 2.425 = - 0.59 J/K
Since S2 - S1 < 0, it violates 2nd law.
d)
No feasibility since it violates 1st law.
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