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Balance the reaction between CIO, and Cr to form CIO3 and Cr3+ in acidic solutio

ID: 1045929 • Letter: B

Question

Balance the reaction between CIO, and Cr to form CIO3 and Cr3+ in acidic solution. When you have balanced the equation using the smallest integers possible, enter the coefficients of the species shown. Cr CiO3 (reactant, product, neither) with a coefficient of (Enter 0 for Water appears in the balanced equation as a neither.) How many electrons are transferred in this reaction? Balance the reaction between Ag and Mn2+ to form Ag and MnO2 in acidic solution. When you have balanced the equation using the smallest integers possible, enter the coefficients of the species shown. Mn2+ Mno2 in the balanced equation as a (reactant, product, neither) with a coefficient of (Enter 0 for Water appears neither.) How many electrons are transferred in this reaction?

Explanation / Answer

1.

Seprate the redox reaction into oxidation half and reduction half reacions.

Oxidation half reaction                                       Redcution half reaction

Cr --------> Cr3+                                ClO4- ----------> ClO3-

2. Balance all aotms other than O and H

Cr --------> Cr3+                                ClO4- ----------> ClO3-

3. To balance oxygen atoms in acidic medium add H2O molecules.

Cr --------> Cr3+                                ClO4- ----------> ClO3- + H2O

4. To balance hydrogen atoms in acidic medium add H+ ions.

Cr --------> Cr3+                                ClO4- +2 H+ (aq.)----------> ClO3- + H2O

5. To balance charges add electrons at more positive charge side.

Cr --------> Cr3+ + 3 e-                  ClO4- +2 H+ (aq.) + 2 e-----------> ClO3- + H2O

6. To equalise electrons in both half reactions, do OHR * 2 and RHR * 3

2 Cr --------> 2 Cr3+ + 6 e-                  3 ClO4- +6 H+ (aq.) + 6 e-----------> 3 ClO3- + 3 H2O

7. Now add the both balanced half reacitons to get balanced redox reaction.

2 Cr --------> 2 Cr3+ + 6 e-        

3 ClO4- +6 H+ (aq.) + 6 e-----------> 3 ClO3- + 3 H2O

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2 Cr + 3 ClO4- + 6 H+ ------------> 2 Cr3+ + 3 ClO3- + 3 H2O

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Verify

Atoms Left Right

Cr         2       2

Cl        3        3

O        12       12

H        6          6

Charge +3    +3

Therefore,

Water appears in the balanced equation as Product with coefficient 3

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