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3c. (BONUS QUESTION) In the copper complexes investigated, the water and ammonia

ID: 970616 • Letter: 3

Question

3c. (BONUS QUESTION) In the copper complexes investigated, the water and ammonia molecules act as Lewis bases (electron pair donors); they provide both of the electrons that form the covalent bonds between the Cu2+ ion and each ligand. Which ligand (H2O or NH3) is the stronger Lewis base? Explain your answer in terms of your answers for questions 3a and 3b. (hint: the poorer an oxidizing agent a species is, the harder it it to reduce that species. Hint #2: the copper complexes are reduced by gaining an electron.)

This is the procedure: http://www3.chem21labs.com/labfiles/UofC_GL23_Lab.pdf?rf=8308

Explanation / Answer

Water and ammonia molecules act as Lewis bases. The spectrochemical series indicates that NH3 is a stronger-field ligand than H2O.

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