A solution containing all of the cations from both Group I and Group IV (look up
ID: 960561 • Letter: A
Question
A solution containing all of the cations from both Group I and Group IV (look up the ions in Group IV) is treated with 6 M HCl. A white precipitte forms.
a) The precipitate contains which "ion(s)"? (Be sure to list the ions individually)
b) The supernatant contains which "ion(s)"? (Be sure to list the ions individually)
Background: Group I Separation Scheme Group l Unknown 6M HCI AgCI, PbCl2, Hg2Cl Groups II, II, IV H20, Heat AgCI, Hg2Cl2 ppt Pb2*(aq) K2Cro 6M NH3 PbCrO yellow ppt,_ Hg / HgNH2CI gray ppt Ag(NH3)2 HNO3 AgCl white pptExplanation / Answer
The precipitate contains group I cations Ag+, Hg2+2 , Pb+2 only. the Group IV cations Ca+2, Ba+2 and Sr+2 remain in the supernatant solution as their chlorides are soluble in water.
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