1.-5. Match each pair of compounds on the left and its corresponding melting poi
ID: 956527 • Letter: 1
Question
1.-5. Match each pair of compounds on the left and its corresponding melting points (m.p.) or boiling points (b.p.) in °C to a major reason, given on the right, why the physical property increases. Answers may be repeated.
CH3CH2PHCH3 (m.p. -160), CH3P(CH3)2 (m.p. -85) a. more weight
CH3N(CH3)2 (m.p. -117), CH3P(CH3)2 (m.p. -85) b. more van der Waal interactions
CH3CH2NHCH3 (b.p. 36), CH3(CH2)2NH2 (b.p. 48) c. more rotational symmetry
(CH3)2CHNH2 (b.p. 33), CH3CH2NHCH3 (b.p. 36) d. more polar bonds
CH3(CH2)2NH2 (b.p. 48), CH3(CH2)2OH (b.p. 97) e. more hydrogen bonds
Explanation / Answer
1)more rotaonal symmetry
2)more molecular weight
3)more H-bonds
4)more rotational symmetry
5)more polarity
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