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Q1) One mole of an ideal gas is sealed in a 22.4-L container at a pressure of 1

ID: 880505 • Letter: Q

Question

Q1)

One mole of an ideal gas is sealed in a 22.4-L container at a pressure of 1 atm and a temperature of 273 K. The temperature is then increased to 304 K , but the container does not expand. What will the new pressure be?

Part A

The most appropriate formula for solving this problem includes only which variables?

Enter the required variables, separated by commas (e.g., P,V,T).

Q2)A sample of nitrogen gas in a 1.69-L container exerts a pressure of 1.37 atm at 17 C.

-What is the pressure if the volume of the container is maintained constant and the temperature is raised to 327 C?

Q3)A gas mixture with a total pressure of 770 mmHgcontains each of the following gases at the indicated partial pressures: 120 mmHg CO2, 227mmHg Ar, and 190 mmHg O2. The mixture also contains helium gas

-What mass of helium gas is present in a 14.0-L sample of this mixture at 282 K ?

Q4)

A

Calculate the density of oxygen, O2, under each of the following conditions:

STP

1.00 atm and 35.0  C

Express your answers numerically in grams per liter. Enter the density at STP first and separate your answers by a comma.

B

To identify a diatomic gas (X2), a researcher carried out the following experiment: She weighed an empty 4.1-L bulb, then filled it with the gas at 2.00 atm and 24.0  C and weighed it again. The difference in mass was 9.5 g . Identify the gas.

Express your answer as a chemical formula.

Explanation / Answer

1- V1=V2=22.4l,    P1=1atm ,   T1=273K , T2 =304K

P1V1/T1 = P2V2 /T2

P2= P1xT2/T1 = 1x304 /273 =1.11355atm

2-V1=V2=1.69L

P1=1.37 T1 = 273+17=290K,   T2 = 273+327 = 600K

P2V2/T2 = P1V1/T1

P2 = P1 xT2 / T1 = 1.37 x 600 /290 =2.8345 atm

3-p total= 770mm

pCO2 =120mm ,   p Ar = 227mm,   pO2 = 190

ptotal = pCo2 + pAr + pO2 + pHe

pHe = 770 - 537 = 233= 0.3066atm

PV = nRT

n= PV /RT = 0.3066 x14/282x0.082 = 4.2924/23.124 = 0 .1856

mass of He = nxMw = 0.1856x4=0.7425g

4-density O2 at STP

1 mole. of O2 = 32g.
1 mole. = 22.4L. at STP
Density = Mass / Volume.
Density of O2 at STP = 32g / 22.4L = 1.43g/L = 1.43kg/m³

P2 = 1atm T2 = 273+35= 308

V2 =?

P1V1/T1 = P2V2/T2

V2 = P1V1xT2/T1 P2=1x22.4 x308 /273x1 = 22.4x1.1282= 25.27

density= mass/volume = 32 / 25.27 = 1.2663g/L