The thermal decomposition of nitryl chloride, NO2Cl, is believed to occur by the
ID: 807609 • Letter: T
Question
The thermal decomposition of nitryl chloride, NO2Cl, is believed to occur by the following mechanism:
NO2Cl(g)?NO2(g)+Cl(g)Cl(g)+NO2Cl(g)?NO2(g)+Cl2(g)
Part A
What is the overall reaction?
What is the overall reaction?
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Part B
What is the molecularity of the first elementary step?
What is the molecularity of the first elementary step?
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Part C
What is the molecularity of the second elementary step?
What is the molecularity of the second elementary step?
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Part D
What rate law is predicted by this mechanism if the first step is rate-determining?
What rate law is predicted by this mechanism if the first step is rate-determining?
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NO2Cl(g)?NO2(g)+Cl2(g) 2NO2Cl(g)?2NO2(g)+Cl2(g) 2NO2Cl(g)?NO2(g)+Cl2(g) NO2Cl(g)?2NO2(g)+Cl2(g)Explanation / Answer
Part A Overall reaction
2NO2Cl(g) -- > 2NO2 + Cl2(g)
Part B Unimolecular
Part C Bimolecular
Part D Rate = k[NO2Cl]
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