The Born-Haber cycle is a series of steps that represent the formation of an ion
ID: 791407 • Letter: T
Question
The Born-Haber cycle is a series of steps that represent the formation of an ionic compound from a metal and a nonmetal. For example, the steps in a Born-Haber cycle for the formation of NaCl(s) consist of sublimation of the metal Na atom (?Hsubl-Na) to form a gaseous Na atom, bond dissociation of the chlorine molecule (BECl2) to form a gaseous Cl atom, ionization energy of the sodium atom (IENa) to form a gaseous Na+ ion, electron affinity of the chlorine atom (EACl) to form a gaseous Cl- ion, and the lattice energy of NaCl (LENaCl) involving the coalescing of the gaseous Na+ and Cl- ions to form a solid NaCl formula unit.
With the above summary in mind, which particular steps of the Born-Haber cycle would be represented in the following reaction?
K(s) + F(g) ? KF(s)
A. ?Hsubl-K, IEK, EAF, and LEKF B. IEK,EAF, and LEKF C. ?Hsubl-K, BEF2, IEK, EAF, and LEKF D. ?Hsubl-K, BEF2, IEK, EAFExplanation / Answer
The answer is:
A. ?Hsubl-K, IEK, EAF, and LEKF
To get the overall reaction: K(s) + F(g) => KF(s)
The following processes are involved:
K(s) => K(g): ?Hsubl-K
K(g) => K+(g) + e-: IEK
F(g) + e- => F-(g): EAF
K+(g) + F-(g) => KF(s): LEKF
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