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1) How many moles of NH,CI and NH,OH must be added to 250 mL of water to make a

ID: 704019 • Letter: 1

Question

1) How many moles of NH,CI and NH,OH must be added to 250 mL of water to make a buffer of pH-9.0? Kb -1.8x10 2) How many milliters of 0.75 M HCI must be added to 120 mL of 0.90 M NaForm to make a buffer of pH -4.0? pKa 3.75 3) What volume of 0.40 M NaOH must be added to 100 mL of 0.60 M H,CO, to make a buffer of pH 10.0? H,CO, H+ + HCO,. KAI-4.2x10" 4) If the pH-3.75 at the endpoint of a titration, which indicator would you use? Circle one. Indicator Range Congo Red Methyl Orange 3.1-4.4 Bromocresol Green 3.8-5.4 3.0-5.0 Methyl Red 4.4-6.2

Explanation / Answer

From the Henderson-Hasselbalch formula,
pOH = pKb + log[NH4+]/[NH4OH]
pOH = 14 - pH = 5
pKb =4.7

log[NH4+]/[NH4OH] = 5 - 4.74 = 0.26

[NH4+]/[NH4OH] = 1.82

So, 1 mole of NH4OH and 1.82 mole sof NH4OH added into 250 ml of water

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