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Organic chemistry Which organic structure is this IR spectrum representing Alcoh

ID: 697324 • Letter: O

Question

Organic chemistry Which organic structure is this IR spectrum representing Alcohol, Aldehydes, Anhydrides, Esters, Ethers, Ketones, unsaturated hydrocarbons? Solubility test: Group 9 Boiling point: Start 160 celcius, Constant: 160 Celsius 70-858 60 50 40 30 20 10 -10 2500 1500 1000 500 Wavenumbers (cm-1) Tue Nov 14 18:56:49 2017 (GMT-05:00) FIND PEAKS: 858 4000.00 Region: Absolute threshold:61.090 Group q 400.00 50 Peak list Position: 725.46 Intensity: 14.487 Position: 891.41 Intensity: 40.115 Position: 920.10 Intensity: 15.818 Position: 1058.25 Intensity: 0.291 Position: 1118.32 Intensity:18.293 Position: 1189.12 Intensity: 37.765 Position: 1223.55 Intensity: 38.808 Position: 1378.73 Intensity: 6.516

Explanation / Answer

The given organic compound is an alcohol

3319.86 cm-1 is due to O-H stretching frequency, broad, strong signal

2923.31 cm-1 is due to sp3 alkyl C-H stretching frequency, strong signal

1378.73 -1467.03 cm-1 is due to sp3 alkyl C-H bending frequency, strong signal

1058.25-1189.12 cm-1 is due to C-O stretching frequency, medium signal

below 1000 cm-1 is fingerprint region, not much useful for prediction of functional groups, just only rocking, twisting, scissoring, wagging vibrational frequencies. Difficult to predict.

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