A. The specific rotation, [] D , for (-)-malic acid is - 27 . What is the observ
ID: 692737 • Letter: A
Question
A. The specific rotation, []D, for (-)-malic acid is -27. What is the observed rotation for a solution of 1.5 g of (-)-malic acid in 10 mL of water in a sample tube having a pathlength of 10 cm?
B. The observed rotation of a solution of 0.92 g of a compound in 10 mL of water is +3.7 degrees. If the pathlength is 10 cm, what is the specific rotation of the compound?
C. The specific rotation, []D, for (-)-malic acid is -27. What is the observed rotation for a solution of 1.2 g of (-)-malic acid in 10 mL of water in a sample tube having a pathlength of 10 cm?
D. The observed rotation of a solution of 1.2 g of a compound in 10 mL of water is +1.3 degrees. If the pathlength is 10 cm, what is the specific rotation of the compound?
Explanation / Answer
A.)
specific rotation = - 27
concentration = 1.5 / 10 = 0.15 g/mL
path length = 10 cm
specific rotation = observed rotation / concentration x length
- 27 = observed rotation / 0.15 x 1
observed rotation = - 4.05
B.)
cocentration = 0.92 / 10 = 0.092 g/mL
specific rotation = 3.7 / 0.092 x 1
specific rotation = 40.2
C)
- 27 = observed rotation / 0.12 x 1
observed rotation = - 3.24
D).
specific rotation = 10.8
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