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A beaker contains 25.00 mL of 0.1000 M acetic acid (HOAc, Ka =1.8x10 -5 ). 0.100

ID: 687903 • Letter: A

Question

A beaker contains 25.00 mL of 0.1000 M acetic acid (HOAc, Ka =1.8x10-5). 0.1000 M NaOH is added from a buret. Assumingthat the volumes are additive, what will be the total solutionvolume in the beaker when the pH is 12.30? Note: the Ph at theendpoint of this titration is 8.72. A beaker contains 25.00 mL of 0.1000 M acetic acid (HOAc, Ka =1.8x10-5). 0.1000 M NaOH is added from a buret. Assumingthat the volumes are additive, what will be the total solutionvolume in the beaker when the pH is 12.30? Note: the Ph at theendpoint of this titration is 8.72.

Explanation / Answer

Titration reaction:                                       CH3COOH (aq) + NaOH (aq) ---------------> CH3COONa (aq) + H2O (l)          Volumeof acetic acid = 25.00 mL Concentration of acetic acid = 0.1000 M       Concentration of NaOH = 0.1000M                                     pH = 12.30                                   pOH = 1.7                                  [OH-] = 0.0199 M                              M1V1 =M2V2                                        V2 = M1V1 /M2                                              =0.1000 M * 0.025 L /0.0199 M                                             = 0.1256 L                                             = 125.6 mL    Total volume of solution inside the beaker = 125.6 mL + 25.0 mL                                                                    =150.6 mL                                        V2 = M1V1 /M2                                              =0.1000 M * 0.025 L /0.0199 M                                             = 0.1256 L                                             = 125.6 mL    Total volume of solution inside the beaker = 125.6 mL + 25.0 mL                                                                    =150.6 mL
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