202 Homework 9 8 10-REDOX & Electrochemistry (2017) 5 pts) Write the oxidation s
ID: 588500 • Letter: 2
Question
202 Homework 9 8 10-REDOX & Electrochemistry (2017) 5 pts) Write the oxidation state for the underlined element in the box following each compou a) NaCIO2 d) HNO3 b) KPO4 c) H20 e) NaCN 5 pts) a) A Ph(NOs)2 solution containing a lead electrode is connected by means of a semi- perm membrane to a MgCl2 solut on containing a magnesium electrode. Which of the following cells representation of the spontaneous reaction that should result to generate electricity (c a) b) c) d) flow of flow of o flow of electrons fow of +2 CI NO No CI Pb Pb Mg CI Pb+2 Pb+ CATHODE ANODE Anic ANODE -+- CATHODE CATHODE- ANODE ANODE Anion fiow Anion flow Anion flow b) Briefly and clearly discuss your reasoning for the cell you selected from part a) below cell potential showing the two half-cell reactions and potentials.Explanation / Answer
a)
Oxidation number of Na = +1
Oxidation number of O = -2
lets the oxidation number of Cl be x
we have below equation to be used:
1* oxidation number (Na) + 2* oxidation number (O) + 1* oxidation number (Cl) = net charge
1*(+1)+2*(-2)+1* x = 0
-3 + 1 * x = 0
x = 3
So oxidation number of Cl = +3
Answer: +3
b)
Oxidation number of K = +1
Oxidation number of O = -2
lets the oxidation number of P be x
we have below equation to be used:
3* oxidation number (K) + 4* oxidation number (O) + 1* oxidation number (P) = net charge
3*(+1)+4*(-2)+1* x = 0
-5 + 1 * x = 0
x = 5
So oxidation number of P = +5
Answer: +5
c)
Oxidation number of H = +1
lets the oxidation number of O be x
we have below equation to be used:
2* oxidation number (H) + 2* oxidation number (O) = net charge
2*(+1)+2* x = 0
2 + 2 * x = 0
x = -1
So oxidation number of O = -1
Answer: -1
d)
Oxidation number of H = +1
Oxidation number of O = -2
lets the oxidation number of N be x
we have below equation to be used:
1* oxidation number (H) + 3* oxidation number (O) + 1* oxidation number (N) = net charge
1*(+1)+3*(-2)+1* x = 0
-5 + 1 * x = 0
x = 5
So oxidation number of N = +5
Answer: +5
e)
Oxidation number of Na = +1
Oxidation number of N = +3
lets the oxidation number of C be x
we have below equation to be used:
1* oxidation number (Na) + 1* oxidation number (N) + 1* oxidation number (C) = net charge
1*(+1)+1*(+3)+1* x = 0
4 + 1 * x = 0
x = -4
So oxidation number of C = -4
Answer: -4
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