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CHM-1: × ' ..,' owLv2 1 Online teaching and x enow.com,/ilrn/takeAssignment/takeCovalentActivity,do?locator-assignment-take&takeAssignmentSessic; Academica 2017 INTERACTIVE EXAMPLE Determining Ka from the Solution pH d, HA, is a monoprotic acid. A solution that is 0.270 M in HA has a pH of2.400 at 25°C. HA(aq) + H2O(l) ,0'(aq) + A-(aq) What is the acid-ionization constant, Ka, for this acid? What is the degree of ionization of the acid in this solution? Degree of ionization- Submit Hide Tutor Steps TUTOR The next step is to construct a table showing the initial concentrations, the change in concentrations, and t sometimes called an ICE table. We call the change in concentration of H3O+ and then use that value to all species. What will be the equilibrium concentration of A, in terms of x? PROBLEM MAP pH 2.400Explanation / Answer
a)
we have below equation to be used:
pH = -log [H+]
2.4 = -log [H+]
log [H+] = -2.4
[H+] = 10^(-2.4)
[H+] = 3.981*10^-3 M
Lets write the dissociation equation of HA
HA -----> H+ + A-
0.27 0 0
0.27-x x x
[H+] = x = 3.981*10^-3 M
Ka = [H+][A-]/[HA]
Ka = x*x/(c-x)
Ka = 3.981*10^-3*3.981*10^-3/(0.27-3.981*10^-3)
Ka = 5.96*10^-5
Answer: Ka = 5.96*10^-5
b)
degree of ionisation = x/c
= (3.981*10^-3)/0.27
= 0.0147
Answer: 0.0147
Feel free to comment below if you have any doubts or if this answer do not work
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