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Item 8 Part A At the transition temperature of 95.4 °C, the enthalpy of transiti

ID: 543828 • Letter: I

Question

Item 8 Part A At the transition temperature of 95.4 °C, the enthalpy of transition from rhombic to monoclinic sulfur is 0.38 kJ mol Calculate the entropy of transition under these conditions Express your answer to two significant figures and include the appropriate units. AStransition 1.0J·K-1-mol-1 - Submit My Answers Give Up Correct Part B The value given in part above is for 1 mol of sulfur; however, in crystalline and liquid sulfur, the molecule is present as Ss. Convert the value of the entropy of transition in part above to those appropriate for S Express your answer to two significant figures and include the appropriate units astransition= 13.14 mol K Submit My Answers Give Up Incorrect; Try Again

Explanation / Answer

Delta S transition= Deltah H transition / Delta T transition

= 0.38 kJ mol^-1 / (273.15+95.4)K

= 1.0 J K^-1 m^-1

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Delta S fusion = Delta H fusion / Delta T fusion

= 1.23 kJ mol^-1 / (273.15+119)K

=3.14 J K^-1 m^-1

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Each of the delta in parts (a) and (b) should be multiplied by 8.

transition delta S = 8.2 J K^-1 mol^-1 -------------------ANSWER

fusion delta S = 25.1 J K^-1 mol^-1

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