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14. 1.Solve all a) Classify each of these compounds as an Arrhenius acid, an Arr

ID: 523544 • Letter: 1

Question

14.

1.Solve all

a)

Classify each of these compounds as an Arrhenius acid, an Arrhenius base, or neither.

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b)The oxyacids containing oxygen (O) and phosphorous (P) are named differently than the oxyanions on which they are based. You have just learned that in general -ite endings are changed to -ous while -ate endings are changed to -ic when naming the acid. However, for the acids of oxyanions based on phosphorus, the root also changes. The roots for the oxyanions and oxyacids of phosphorus are shown below.

oxyanion root: phosph

oxyacid root: phosphor

Although the exception exists for the root, the prefixes and suffixes of these oxyacids still follow the conventions for naming oxyacids. Using the table of oxyanions given in the transition before Part B and the roots shown above, give the name of the oxyacid H3PO3 below.

Spell out the full name of the acid.

c)

Carbonic acid reacts with water to yield bicarbonate ions and hydronium ions:

H2CO3+H2OHCO3+H3O+

Identify the conjugate acid-base pairs.

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Bins

Acid

Conjugate base

Base

Conjugate acid

d)

Classify each of these compounds as a Brønsted-Lowry acid, a Brønsted-Lowry base, or neither.

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HCIO

Explanation / Answer

(a)

Arrhenius acid: The species that produce H+ ions (potons) in aqueous medium are called acids.

Arrhenius base: The species the produce OH- ions (hydroxyl) in aqueous medium are called bases.

HClO3 Arrhenius acid

NaOH Arrhenius Base

H3PO4 Arrhenius acid

HCl       Arrhenius acid

Zn(OH)2 Arrhenius Base

KCl          Neither

Hg(OH)2   Arrhenius Base

Al(OH)3    Arrhenius Base

HBr         Arrhenius acid

C3H8     Neither

(b) H3PO3 = Phophorous acid

(c) An acid base pair differed by only one proton is called conjugate acid - base pair.

H2CO3 and HCO3- is a conjugate acid - base pair.

H3O+ and H2O is a conjugate acid - base pair.

(d) Bronsted - Lowry acid : Proton donor

Bronsted - Lowry base: Proton acceptor

HCl Acid

HBr Acid

HClO4 Acid

(C2H5)2NH Base

C2H5NH2 Base

NH3 Base

KBr Neither

CH2Cl2 Neither

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