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The question is asking to explain why PbCl4 exists, while PbBr4 and PbI4 do NOT

ID: 486480 • Letter: T

Question

The question is asking to explain why PbCl4 exists, while PbBr4 and PbI4 do NOT exist. Here is what I have found, is this correct?

Upon ionization: PbI4----> Pb^4+ + 4I^-

The I^- wil be oxidized, and reduce Pb^4+ to Pb^2+ and in the process I2 will form. This is because the oxidation potential of I^- is much higher than that of Cl^- (since the oxidation potential of Cl- is relatively low, it does not act as a reducing agent to reduce Pb^4+).

(The exact same reasoning is applied to why PbBr4 does not exist also)

Explanation / Answer

Due to bigger size of these ions, they have more reducing power(i.e. I- reduces Pb(+4) to Pb(+2) and itself oxidises from I- to I2). Similar reason for PbBr4.

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