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The image below shows an insulated container with an “A” and a “B” compartment t

ID: 1940405 • Letter: T

Question

The image below shows an insulated container with an “A” and a “B” compartment that are separated by a membrane that is designed to rupture at a pressure of 2 MPa.

Compartment A has a volume of 0.03 m3 and contains a vacuum.

Compartment B has a volume of 0.014 m3 and contains 1.1 kg of R-134a at 25oC

The R-134a is stirred by the fan until the membrane ruptures. When this happens:

A)    Determine the temperature of the R-134a

B)    Calculate the work done by the fan

C)    Determine the final pressure and temperature after the membrane ruptures and the R-134a reaches thermodynamic equilibrium.

Explanation / Answer

The membrane ruptures, that means the pressure of R134a in compartment B is 2Mpa,

mol wt of R134a = 102.03 g/mol

no. of moles of R134a = 1.1x1000/102.03 = 10.7811 moles

R = 8.314 J/(K-mol)

Temperature T of R134a = PV/nR = 2x106x0.014/(10.7811x8.314) = 312.38 K

pressure of R134a at 25C initially = nRT/V = 10.7811x8.314x298/0.014 = 1.9MPa

work done by Fan = VBP = 0.014(2-1.9) = 1.4kJ

since its a free expansion, work done by gas during expansion will be zero,so,

final presssure of the R134 = 2Mpa, final temperature = 312.38 K......................if gas behaves ideally