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A bubble of 5.00 mol helium is submerged at a certain depth in liquid water when

ID: 1479344 • Letter: A

Question

A bubble of 5.00 mol helium is submerged at a certain depth in liquid water when

the water ( and thus the helium ) undergoes a temperature increase T of 16C at

constant pressure. As a result, the bubble expands.

(a) How much heat Q is added to the helium during the expansion and temperature

increase?

(b) What is the change Eint in the internal energy of the helium during the temperature increase?

(c) How much work W is done by the helium as it expands against the pressure of

the surrounding water during the temperature increase?

Explanation / Answer

Cp -Cv =R

Cp = specific heat at constant pressure

Cv = specific heat at constant volume = (3/2)R

R =8.314 J/mol.K

dT =16 oC

(a) At constant pressure

Q = nCpdT =n(Cv+R)dT

Q = 5*(5/2)*8.314*16

Q= 1662.8 J

(b) Change internal energy Eint = nCvdT

Eint = 5*(3/2)*8.314*16 = 997.68 J

(c) From first law of thermodynamics

Q = Eint +W

W =Q -Eint = 1662.8 -997.68

W = 665.12 J