Determine the stereo-chemical relationships of molecules A-D by compare all of t

Question

Determine the stereo-chemical relationships of molecules A-D by compare all of the molecules (A-D) to he Lead Compound given below. The possible relationships are, mesomeric (M) same (S), enantiomeric (E) and diastercomeric (D). Note, conformational changes have no influence on the configuration. Lead Compound to D .nswer: relationships of Lead to A to , to C , to D. 5)-Determine the number of chiral centers (ie., Indicate byusing *) for compound “A" below, and determine the absolute configurations (i.e., R or S) of 6 chiral carbon centers amongst compound "A" below. "Place appropriate R or S symbols immediately next to the appropriate chiral carbon center" Answer (# of Chiral Centers): Br

Explanation / Answer

A to B is same since both structure can be acheived by flipping the molecule

A to C is diastereomers since both does not have mirror image relationship

A to D is enantiomers since both having mirror image relationship and not superimposable

Lead to A and lead to B are diastereomers since both pair does not have mirror image relationship

Lead to C are same compound since both the structure acheived by flipping of the molecule

Lead to D are enantiomers since both having mirror image relationship and not superimposable

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