It is known that the kinetics of recrystallization for some alloy obey the Avram
ID: 1064340 • Letter: I
Question
It is known that the kinetics of recrystallization for some alloy obey the Avrami equation, and that the value of n in the exponential is 4.5. If, at some temperature, the fraction recrystallized is 0.30 after 100 min, determine the rate of recrystallization at this temperature. It is known that the kinetics of recrystallization for some alloy obey the Avrami equation, and that the value of n in the exponential is 4.5. If, at some temperature, the fraction recrystallized is 0.30 after 100 min, determine the rate of recrystallization at this temperature.Explanation / Answer
Since it's given that..the kinetics of recrystallization for some alloy obey the avrami equation... But we know that..Avrami equation is
Xc(t) = 1-exp(-Ktn)
Xc(t)= Normalised crystalline content at time t
K,n are avrami constants t= 100 min n=4.5 Xc(t)= 0.3 exp(-ktn) - ln(1-y) (-ktn) - ln(1-y) k = -ln(1-y)/tn
k= -ln(1-0.30)/(1004.5) k= 3.5667*10-10 tn = -ln(1-y)/k
t ={-ln(1-y)/k}1/n t0.5 = [-ln(1-0.5)/3.5667*10-10 ]1/4.5
t0.5 = 4.165621*10-3 min
now rate= 1/t0.5
= 1/4.165621*10-3
=240.06 min-1
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