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Ionic Compound Mass (g) T i ( ° C ) Tf (°C) T (°C) q (J) H (J/mol) Calcium chlor

ID: 1056400 • Letter: I

Question

Ionic Compound

Mass (g)

T i (°C )

Tf (°C)

T (°C)

q (J)

H (J/mol)

Calcium chloride

5g

22°C

34°C

+12°C

-251J

Ammonium nitrate

5g

22°C

16°C

-6°C

+125J

Magnesium Carbonate

2g

21°C

21°C

0°C

0

Sodium chloride

5g

21°C

20°C

-1°C

+21J

Cs (water) = 4.18 J/g-°C , Density of water = 1g/mL

Q) Are my calculations for q (J), correct?

Q) Calculate: H (J/mol), for the four ionic compounds?

1. Which (if any) of the reactions were endothermic? Which (if any) of the reactions were exothermic? If no conclusion can be made, write no conclusion. Explain how you used the data you collected to decide if the reactions were endo- or exothermic.

2. If a reaction is exothermic, are the attractive forces between the reactants stronger or weaker than the attractive forces between the products? Explain your answer.

3. Examine the groups of salts whose dissolution was endothermic and those that were exothermic. Discuss the IMF that exists between solute molecules, solvent molecules (water) and between the solute and the solvent. Use IMF to rationalize the heat transfer for each molecule upon dissolution.

Ionic Compound

Mass (g)

T i (°C )

Tf (°C)

T (°C)

q (J)

H (J/mol)

Calcium chloride

5g

22°C

34°C

+12°C

-251J

Ammonium nitrate

5g

22°C

16°C

-6°C

+125J

Magnesium Carbonate

2g

21°C

21°C

0°C

0

Sodium chloride

5g

21°C

20°C

-1°C

+21J

Explanation / Answer

endothermicreaciton there is a temperature drop during the course of reaction. this is happening in ammoniu8m nitrate and sodium chloride. So the dissolutinos are endothermic

the attracitve forces between the reactant is weaker than products. the excess energy li liberted in the form of heat.

3. when the attractive forces between the reactns molecules is stronger than products, heat has to be supplied to brea k the reactants. leading to endothermic reaction.

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