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help me with the right answers please Possible Products from the Hydrochlorinati

ID: 1052149 • Letter: H

Question

help me with the right answers please

Possible Products from the Hydrochlorination of Carvone Cl 2 4 5 How many different types of carbon are present? How many signals should be present? How many peaks should be present in the 0-50 ppm range? How many peaks should be present in the 50-100 ppm range? How many peaks should be present in the 100-150 ppm r How many peaks should be present in the above 150 ppm? How many CH3 groups should be present in the DEPT? How many CH2 groups should be present in the DEPT? How many CH groups should be present in the DEPT? How many carbons have no hydrogen attached?

Explanation / Answer

Table

                                                   2             3               4           5

Different types of C                     9             10             10       10

number of signals                       9             10             10       10                  

peaks in 0-50 ppm                       6            6              6       6

peaks in 50-100 ppm                   1              1           1       1

peaks in 100-150 ppm                 2              2               2        2

peaks above 150 ppm                 1              1               1        1

CH3 in 13C                                  3              2               2        2

CH2 in 13C                                  2              3               3        2

CH in 13C                                    2              3               1        1

quaternary C in 13C                     3              2               3        2

A) The 100-150 region and above 150 ppm would have major changes in from reactant to product formation.

B) Based on the electrophilic addition reaction, product 2 would eb the preferred as isolated alkeneare more electron rich for addition reaction and product with most substituted carbon with Cl is formed as major product by a carbocation intermediate.