1. In the photographic developing process, silver bromide is dissolved by adding
ID: 1006617 • Letter: 1
Question
1.
In the photographic developing process, silver bromide is dissolved by adding sodium thiosulfate.
AgBr(s) + 2 Na2S2O3(aq) Na3Ag(S2O3)2(aq) + NaBr(aq)
If you want to dissolve 0.194 g of AgBr, what volume of 0.0138 M Na2S2O3, in milliliters, should be used?
_____mL
2.
What volume of 0.226 M NaOH, in milliliters, contains 25.0 g of NaOH ?
Volume = ______mL
3.
The reaction of methane and water is one way to prepare hydrogen for use as a fuel:
CH4(g) + H2O(g) CO(g) + 3 H2(g)
What mass of the excess reactant remains when the reaction is completed if the limiting reactant is H2O?
_______ g of the excess reactant
Explanation / Answer
(1) AgBr(s) + 2 Na2S2O3(aq) Na3Ag(S2O3)2(aq) + NaBr(aq)
Molar mass of AgBr is 188 g/mol
Given mass of AgBr = 0.194 g
Number of moles , n = mass/molar mass
= 0.194 / 188
= 0.001 moles
According to the balanced reaction ,
1 mole of AgBr reacts with 2 moles of Na2S2O3
0.001 mole of AgBr reacts with M moles of Na2S2O3
M = ( 0.001x2) / 1
= 0.002 moles
So Volume of Na2S2O3 is , V = number of moles / molarity
= 0.002 mol / 0.0138
= 0.149 L
= 149 mL
(2) What volume of 0.226 M NaOH, in milliliters, contains 25.0 g of NaOH ?
We know that Molarity , M = ( mass/Molar mass) x ( 1000/Volume in mL)
0.226 = ( 25.0/40) x ( 1000 / Volume in L)
So Volume of the solution , V = 2765 mL
(3) This reaction is incomplete.It involves the masses of the reactants.
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