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PLS only answer if you know what you\'re doing and if you are going to answer al

ID: 1002859 • Letter: P

Question

PLS only answer if you know what you're doing and if you are going to answer all of them, i got alot to do cuz of finals so i'd appreciate it if you answer them all correctly, thank you

1) Calculate the standard emf (electromotive force) for a voltaic cell whose cell reaction is represented by the balanced equation.

2H2O(l) H2(g) + H2O2(aq)

2) Calculate the standard cell potential for a galvanic cell whose cell reaction is represented by the balanced equation.

2Fe(s) + 3I2(s) 2Fe3+(aq) + 6I-(aq)

St. Red. Pot. (V)

3) For the voltaic cell shown, calculate the standard cell potential.

Pt(s) l H2O(l), H2O2(aq), H+(aq) ll H+(aq) l H2(g), Pt(s)

0

4)For the voltaic cell shown, calculate the standard cell potential.

Mn(s) l Mn2+(aq) ll F2(g) l F-(aq) l Pt(s)

St. Red. Pot. (V)

2.87

5)For the galvanic cell shown, calculate the Eo.

Fe(s) l Fe2+(aq) ll Cd2+(aq) l Cd(s)

St. Red. Pot. (V)

6) The value for the standard emf of a voltaic cell described by the cell notation is 1.88 V. Determine the value (V) of the standard half cell potential for the F2/F- couple.

Au(s) l AuCl4-(aq), Cl-(aq) ll F2(g) l F-(aq) l Pt(s)

St. Red. Pot. (V)

1) Calculate the standard emf (electromotive force) for a voltaic cell whose cell reaction is represented by the balanced equation.

2H2O(l) H2(g) + H2O2(aq)

2) Calculate the standard cell potential for a galvanic cell whose cell reaction is represented by the balanced equation.

2Fe(s) + 3I2(s) 2Fe3+(aq) + 6I-(aq)

St. Red. Pot. (V)

Fe3+/Fe -0.04 I2/I- 0.54

3) For the voltaic cell shown, calculate the standard cell potential.

Pt(s) l H2O(l), H2O2(aq), H+(aq) ll H+(aq) l H2(g), Pt(s)

St. Red. Pot. (V) H2O2/H2O 1.78 H+/H2

0

4)For the voltaic cell shown, calculate the standard cell potential.

Mn(s) l Mn2+(aq) ll F2(g) l F-(aq) l Pt(s)

St. Red. Pot. (V)

Mn2+/Mn -1.18 F2/F-

2.87

5)For the galvanic cell shown, calculate the Eo.

Fe(s) l Fe2+(aq) ll Cd2+(aq) l Cd(s)

St. Red. Pot. (V)

Fe2+/Fe -0.44 Cd2+/Cd -0.40

6) The value for the standard emf of a voltaic cell described by the cell notation is 1.88 V. Determine the value (V) of the standard half cell potential for the F2/F- couple.

Au(s) l AuCl4-(aq), Cl-(aq) ll F2(g) l F-(aq) l Pt(s)

St. Red. Pot. (V)

AuCl4-/Au 0.99 St. Red. Pot. (V) H2O2/H2O 1.78 H+/H2 0

Explanation / Answer

1) Eocell = 0-1.78

                 = -1.78 V

2)   oxidation : Fe-------------------> Fe+3 + 3e-

     reduction : I2 + 2e- ---------------> 2I-

Eocell = Eored - Eo oxd

            = 0.54 - (-0.04)

             = 0.58 V

Eocell = 0.58 V

3) similarly

Eocell = -1.78 V

4)

Eocell = 2.78 - (-1.18)

          = 3.96 V

5)

Eocell= -0.40 - (-0.44)

           = 0.04 V

6)

Eocell= Eo red - Eo oxd

1.88 = Eo red - 0.99

Eo red = 2.87 V

Eo F2/F = 2.87 V

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