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How to find moles given oxidation numbers and chemical formula? Trying to do my

ID: 999675 • Letter: H

Question

How to find moles given oxidation numbers and chemical formula? Trying to do my chemistry lab but i'm stuck. this is the part i'm stuck on:

The overall charge on the complex, [Ni(en)(H2O)]^2+ * SO4^2- * H2O is zero; the charge on sulfate ion is 2-;en and water ligands both have a charge of zero; and nickel has a charge of 2+. Using this information and your previous experimental results, calculate the number of moles of SO4^2- in 100 grams of your complex and the mass percent of SO4^2- in your complex.

previous experimental results: Molarity of Ni^2+ in unknown sample: 0.036M.

Moles of Ni^2+ in 100 g of complex: 0.345 moles

Mass % of Ni^2+ in complex: 20.24%

Explanation / Answer

Solution:- from the given complex formula, there is 1:1 mole ratio between Ni+2 and SO4-2. there are 0.345 moles of Ni+2, So, the moles of SO4-2 are also 0.345.

molar mass of SO4-2 is (32 + 4*16 = 96 g/mol)

So, 0.345 mol x (96g/1mol) = 33.12g

mass percent od SO4-2 = (mass of SO4-2/mass of complex) x 100 = (33.12/100) x 100 = 33.12%

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