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Ten test tube mystery We will be given ten unlabeled test tubes. Using the test

ID: 991068 • Letter: T

Question

Ten test tube mystery

We will be given ten unlabeled test tubes. Using the test tube contents and absolutely nothing else, we must identify the contents of each testtube. Each test tube will contain one of the following:

Ni(NO3)2

Al(NO3)3

SnCl4 in HCl

Cu(NO3)2

AgNO3

Ca(NO3)2

NH3

NaOH

H2SO4

HCl

We must create a reaction matrix. I have created one but would like it to be corrected or emphasized.

ppt= precipitate

NR= no reaction

D= precipiates dissolves in excess

Ni(NO3)2

Al(NO3)3

SnCl4 in HCl

Cu(NO3)2

AgNO3

Ca(NO3)2

NH3

NaOH

H2SO4

HCl

Ni(NO3)2

NR

Al(NO3)3

SnCl4 in HCl

Cu(NO3)2

AgNO3

Ca(NO3)2

NH3

NaOH

HCl

Ni(NO3)2

Al(NO3)3

SnCl4 in HCl

Cu(NO3)2

AgNO3

Ca(NO3)2

NH3

NaOH

H2SO4

HCl

Ni(NO3)2

NR NR NR NR

NR

NR D, BLUE SOLUTION PPT NR NR

Al(NO3)3

NR NR NR NR NR PPT PPT, D NR NR

SnCl4 in HCl

NR GREEN SOLUTION PPT NR PPT, HEAT PPT, D, HEAT NR NR

Cu(NO3)2

NR NR NR PPT, D PPT NR GREEN SOLUTION

AgNO3

NR NR BROWN PPT, D BROWN PPT PPT PPT

Ca(NO3)2

NR PPT PPT NR NR

NH3

NR HEAT HEAT HEAT

NaOH

NR HEAT PPT, HEAT H2SO4 NR NR

HCl

NR

Explanation / Answer

Corrections/additions to the table content

Al(NO3)2

Al(NO3)3 with NaOH forms ppt of Al(OH)3 which Dissolved in excess OH- to form Al(OH)4-.

Al(OH)3 with NH3 forms ppt of Al(OH)3

Cu(NO3)2

Reacts with NH3 to form [Cu(NH)3]2+ deep blue solution

Reacts with aq.H2SO4 to form CuSO4 which is blue in color

AgNO3

Reacts with SnCl4 to form ppt of AgCl

Ca(NO3)2

Reacts with H2SO4 to form ppt of CaSO4

Reacts with HCl to form ppt of CaCl2

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