Assuming 100% dissociation, calculate the freezing point and boiling point of 1.
ID: 985768 • Letter: A
Question
Assuming 100% dissociation, calculate the freezing point and boiling point of 1.52 m SnCl4(aq). Constants may be found here.
(°C/m)
Normal freezing
point (°C)
(°C/m)
Normal boiling
point (°C)
vent Formula Kf value*(°C/m)
Normal freezing
point (°C)
Kb value(°C/m)
Normal boiling
point (°C)
water H2O 1.86 0.00 0.512 100.00 benzene C6H6 5.12 5.49 2.53 80.1 cyclohexane C6H12 20.8 6.59 2.92 80.7 ethanol C2H6O 1.99 –117.3 1.22 78.4 carbontetrachloride CCl4 29.8 –22.9 5.03 76.8 camphor C10H16O 37.8 176
Explanation / Answer
I have solved the first four sub-parts, please post one more question to get the remaining answer
Vont hoff factor for SnCl4 (i) = 5
Depression in Freezing point of water= i * KF * m
=> 5 * 1.86 * 1.52
=> 14.136
Hence freezing point of water = -14.136C
Elevation in boiling point of water= i * Kb * m
=> 5 * 0.512 * 1.52
=> 3.8912
Hence boiling point of water = 103.8912 C
Depression in Freezing point of benzene= i * KF * m
=> 5 * 5.12 * 1.52
=> 38.912
Hence freezing point of benzene = -33.422C
Elevation in boiling point of benzene = i * Kb * m
=> 5 * 2.53 * 1.52
=> 19.228
Hence boiling point of benzene = 99.328 C
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