For the reaction 4 A( g ) + 3 B( g ) 2 C( g ) the following data were obtained a
ID: 985384 • Letter: F
Question
For the reaction
4 A(g) + 3 B(g) 2 C(g)
the following data were obtained at constant temperature.
(a) What is the order with respect to each reactant?
(b) Select the rate law.
a. rate = k[A]2[B]rate = k[A] b. rate = k[A]3[B]1/2 c.rate = k[B]2 d.rate = k[A][B]2 e.rate = k[A]1/2[B]3
(c) Calculate k (using the data from Expt 1).
________L2/mol2·min
(mol/L·min) Initial [A]
(mol/L) Initial [B]
(mol/L) 1 5.00 0.100 0.100 2 45.0 0.300 0.100 3 10.0 0.100 0.200 4 90.0 0.300 0.200
Explanation / Answer
a) by doubling the concentration A rate increases two times.
so with respect to A second order.
by doubling the concentration of B rate also doubled.
so with respect to B first order.
b) rate = k[A]2[B]
c) K = rate / [A]2[B]
K = 5.0 / (0.1)2 (0.1)
K = 5.0 x 103 L2/mol2·min
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