13. The concentration of iodide ions in a saturated solution of lead (II) iodide
ID: 967980 • Letter: 1
Question
13. The concentration of iodide ions in a saturated solution of lead (II) iodide is ________ M.
The solubility product constant of PbI2 is 1.4 x 10-8.
[A] 1.4 x 10-8 [B] 1.5 x 10-3 [C] 3.5 x 10-9 [D] 3.8 x 10-4 [E] 3.0 x 10-3
14. The solubility of lead (II) chloride (PbCl2) is 1.6 x 10-2 M. What is the Ksp of PbCl2?
[A] 4.1 x 10-6 [B] 1.6 x 10-5 [C] 3.1 x 10-7 [D] 5.0 x 10-4 [E] 1.6 x 10-2
15. The solubility of manganese (II) hydroxide (Mn(OH)2) is 2.2 x 10-5 M. What is the Ksp of
Mn(OH)2?
[A] 2.2 x 10-5 [B] 2.1 x 10-14 [C] 1.1 x 10-14 [D] 4.8 x 10-10 [E] 4.3 x 10-14
16. Which of these expressions correctly expresses the solubility-product constant for
Ag3PO4 in water?
[A] [Ag][PO4] [B] [Ag+][PO43] [C] [Ag+]3[PO43]
[D] [Ag+][PO43]3 [E] [Ag+]3[PO43]3
17. A solution of NaF is added dropwise to a solution that is 0.0166 M in Ba2+. When the
concentration of F- exceeds ________ M, BaF2 will precipitate. Neglect volume changes.
For BaF2, Ksp = 1.7 10-6.
[A] 1.0 x 10-2 [B] 1.0 x 10-4 [C] 5.1 x 10-5 [D] 2.5 x 10-3 [E] 2.8 x 10-8
18. A solution contains 2.3 x 10-4 M Ag+ and NaI solution is being added drop wise. What
is the minimum concentration of I- to begin precipitation of AgI? Ksp (AgI)= 8.3 x 10-17
[A] 8.32 x10-17 M [B] 2.51 x 10-17 M [C] 3.01 x 10-15
[D] 3.51 x 10-14 M [E] 3.61 x 10-13 M
Explanation / Answer
PbI2(aq) <-------------> Pb^2+(aq) + 2I-(aq)
Ksp = [Pb^2+] [I-]^2
1.4 x 10^-8 = [x][2x]^2
1.4 x 10^-8 = 4x^3
x^3 = 4.67 x 10^-9
x = 1.67 x 10^-3
Thus, Concentration of I- = [I-] = 2x = 2 x 1.67 x 10^-3 = 3.34 x 10^-3 M
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