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How to express the van\'t Hoff factor Here are three different methods of expres

ID: 966657 • Letter: H

Question

How to express the van't Hoff factor Here are three different methods of expressing the van't Hoff factor: Part A At what temperature would a 1.65 solution freeze, given that the van't Hoff factor for NaCl is 1.9? for water is 1.86 . Express your answer with the appropriate units. 3.2 Units SubmitHintsMy AnswersGive UpReview Part Part B A 0.050 solution of had an observed osmotic pressure of 3.85 at 20 . Calculate the van't Hoff factor for . Express your answer numerically. = m SubmitHintsMy AnswersGive UpReview Part

Explanation / Answer

A)

Freezing point of water, Tf = 0 oC

Depression in freezing point, Tf = i Kf m

i = 1.9

Kf = 1.86 °C kg mol-1

Molality, m = 1.65 mol kg-1

Tf = (1.9) * (1.86 °C kg mol-1) (1.65 mol kg-1)

Tf = 5.83 °C

Freezing point = Tf - Tf = -5.83 °C

B)

Osmotic pressure, = i C RT

Molarity, C = 0.05 M

Osmotic pressure, = 3.85 atm

T = 20 °C = 293.15 K

3.85 atm = i * (0.05 mol/L) * (0.0821 L atm / mol-K) * 293.15 K

i = 3.2

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