The half-equivalence point of a titration occurs half way to the end point, wher
ID: 962750 • Letter: T
Question
The half-equivalence point of a titration occurs half way to the end point, where half of the analyte has reacted to form its conjugate, and the other half still remains unreacted.
If 0.300 moles of a monoprotic weak acid (Ka = 1.5 × 10-5) is titrated with NaOH, what is the pH of the solution at the half-equivalence point?
thanks
Explanation / Answer
by definition, the H in the half equivalence point is given by pKa
since
pH = pKa + log(conjugate/acid)
and
(conjugate/acid) = 1
so
log(1) = 0
pKa = -logKa = -log(1.5*10^-6) = 5.82390
pH = 5.82390
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