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10 &11 The freezing point of 21 2 g of NaCl in 135 mL of water (K_r = 1.86 C/m)

ID: 950340 • Letter: 1

Question

10 &11 The freezing point of 21 2 g of NaCl in 135 mL of water (K_r = 1.86 C/m) is -5.00 degree C -4.60 degree C 9.99 degree C 11.5 degree C The reaction 2N_2O_5(g) 2N_2O_4 (g) + O_2(g) obeys the rate law rate = k[N_2O_5]. In which the specific rate constant is 0.00840 s^-1. If 2.50 moles of N_2O_5 were placed in a 5.0-liter container at that temperature, how many moles of N_2O_5 would remain after 1.00 minute? The rate of the reaction A aB when [A] = 0.2 M is 3 2 Times 10^-2 Ms^-1 If the reaction is second order in A, the rate constant is M^-1s^-1. The gas-phase decomposition of NOBr is second order in [NOBr], with k = 0.810 M^-1 s^-1

Explanation / Answer

10. IT is a first order reaction

K = (1/t)ln(a/x)

0.0084 = (1/60)ln(2.5/x)

x= 1.51 mol

No ofmol of N2O5 remain after 1 min = 1.51 mol

11.

rate = k[a]^2

k = 3.2*10^(-3)/(0.2^2)

= 0.08

Dr Jack
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