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(a) In a chemical reaction a solid decomposes to form two different gases. Would

ID: 945362 • Letter: #

Question

(a) In a chemical reaction a solid decomposes to form two different gases. Would you expect DS to be positive, negative, or close to zero for this reaction?


DS for this reaction should  ---Select--- be positive be negative be close to zero .





(b) In which of the processes described below should the entropy increase? Choose all of the correct possibilities.

ice cubes melting at -5 oC and 1 atm pressure

water disappearing from a tea kettle by boiling away

gas sprayed onto a cold surface deposits (solidifies) and becomes part of the surface

dissolution of sugar in a hot cup of coffee

some dry ice left on a tabletop disappearing via sublimation

Explanation / Answer

a) positive.

solid -------------> gas + gas

here gas has more disorder than solid particles. so entropy increases. positive.

b)

a) ice cubes melting at -5 oC and 1 atm pressure

b) water disappearing from a tea kettle by boiling away

c) dissolution of sugar in a hot cup of coffee

d) some dry ice left on a tabletop disappearing via sublimation

these all four cases, disorder of molecules increases. so entropy increases.