Which of the following represents a propagation step in the chloriatino of chlor

Question

Which of the following represents a propagation step in the chloriatino of chloride (Ch_2Cl_2)? Rank the following radicats in order of decreasing stability (most stable to least stable). Which of the following would you expect to function as an initiator at the lowest temperature? Predict the major product obtained upon radical bromination of t-butylcyclohexane. 2-bromo-1-t-butylcyclohexane 1-bromo-1-t-butylcyclohexane 3-bromo-1-t-butylcyclohexanc 4-bromo-1-t-butylcyclohexane (1-bromo-1,1-dimothyl)ethylcyclohexane Predict the major product(s) of the following reaction.

Explanation / Answer

1) (A) represents the propagation step

2) tertiary carbocations and allylic carbocations are most stable

Thus, the correct order is :- (E)

3) (D) will function as an initiator

4) The major product will be I & IV

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