1. What is the mass of sulfuric acid, H2SO4, in 25.0 mL of 12.0 M sulfuric acid?
ID: 928082 • Letter: 1
Question
1. What is the mass of sulfuric acid, H2SO4, in 25.0 mL of 12.0 M sulfuric acid?
2. If 25.0 mL of 0.150 M aluminum bromide reacts with 15.0 mL of 0.200 M silver nitrate, what mass of silver bromide is produced? _AlBr3 (aq) +_AgNO3 (aq) -> _AgBr (s) + _Al(NO3)3 (aq)
3. What is the molarity of aluminum ions in the above question before the reaction has taken place? (Above Question 2)
4. Calculate the boiling point of a 0.4500 m solution of ethylene glycol.
5. What is the pH of a 5.40 x 10^-2 M barium hydroxide solution?
Explanation / Answer
1. What is the mass of sulfuric acid, H2SO4, in 25.0 mL of 12.0 M sulfuric acid?
Solution :- Lets first calculate the moles of H2SO4
Moles of H2SO4 = molarity * volume in liter
= 12.0 mol per L * 0.025 L
= 0.300 mol
Mass of H2SO4 = moles * molar mass
=0.300 mol * 98.08 g per mol
= 29.4 g H2SO4
2. If 25.0 mL of 0.150 M aluminum bromide reacts with 15.0 mL of 0.200 M silver nitrate, what mass of silver bromide is produced? _
Solution :-
Balanced reaction equation
AlBr3 (aq) +3AgNO3 (aq) -> 3AgBr (s) + Al(NO3)3 (aq)
Lets calculate the moles of each reactant
Moles of AlBr3 = 0.150 mol per L * 0.025 L = 0.00375 mol
Moles of AgNO3 = 0.200 mol per L * 0.015 L = 0.003 mol AgNO3
Moles of AgNO3 are less than moles of AlBr3
And mole ratio is 1 mol AlBr3 = 3 mol AgNO3
Therefore AgNO3 is the limiting reactant
So the moles of AgBr that can be formed are calculated
0.003 mol AgNO3 * 3 mol AgBr / 3 mol AgNO3 = 0.003 mol AgBr
Now lets convert moles of AgBr to its mass
Mass of AgBr = moles * molar mass
= 0.003 mol * 187.77 g per mol
= 0.563 g AgBr
3. What is the molarity of aluminum ions in the above question before the reaction has taken place? (Above Question 2)
Solution :- AlBr3 concetration = 0.150 M so the molarity of the Al^3+ = 0.150 M in the original solution 25.0 ml
When they mixed then volume changes to 25 +15 = 40 ml
So the concentration of the Al^3+ ion = 0.150 M * 25.0 ml / 40.0 ml = 0.0938 M
4. Calculate the boiling point of a 0.4500 m solution of ethylene glycol.
Solution :-
Delta Tb = Kb * m
Kb of water is 0.512 C/m
Delta Tb = 0.512 C per m * 0.4500 m
Delta Tb = 0.2304 C
So the boiling point of solution is
BP of solution = 100 C + 0.2304 C = 100.23 C
5. What is the pH of a 5.40 x 10^-2 M barium hydroxide solution?
Solution :- Ba(OH)2 ----- > Ba^2+ + 2 OH-
So the concentration of the OH- = 5.40*10^-2 M * 2 = 1.08*10^-1 M
pOH= -log [OH-]
pOH = -log [1.08*10^-1]
pOH= 0.97
pH + pOH= 14
pH= 14 – pOH
pH= 14 – 0.97
pH = 13.03
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