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1. What change would you expect on the rate of the S N 2 reaction of 1-iodo-2-me

ID: 921902 • Letter: 1

Question

1. What change would you expect on the rate of the SN2 reaction of 1-iodo-2-methylbutane with cyanide ion if the nucleophile concentration is halved and the alkyl halide concentration is halved?

Possible answers: divided by 4, halved, no effect, increased 2x, increased 3x, increased 6x, increased 9x

2. What change would you expect on the rate of the reaction of ethanol with 2-iodo-2-methylbutane if the nucleophile concentration is unchanged and the alkyl halide concentration is tripled?

Possible answers: divided by 4, halved, decreased, no effect, increased 2x, increased 3x, increased 6x, increased 9x

Explanation / Answer

1 ) answer : divided by 4

2) answer : increased 3x

explanation:

1) SN2 reaction : rate = k [RX] [nucleophile]

                               = k [RX /2 ] [nucleophile / 2]

                               = rate / 4

2) rate = k [RX]

              = k [3 RX]

              = 3 rate