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The conversion of an alkyne into an alkene can occur selectively to give two iso

ID: 920648 • Letter: T

Question

The conversion of an alkyne into an alkene can occur selectively to give two isomeric products, G and I The choice of substrate and reaction conditions plays a pivotal role in selecting the desired stereo isomenc product Using the incorrect conditions will lead to completely different compounds Select the correct descriptor of compounds G and I: identical, constitutional isomers, diastereomers, or enantiomers. Select the correct descriptor of compounds H and J: identical, constitutional isomers, diastereomers, or enantiomers. For reactions involving alkenes, it is very important to consider if a reaction will occur by a syn or anti pathway because of the stereochemical consequences of the product. For reactions involving alkenes. it is very important to consider if a reaction will give the Markovnikov or anti-Markovnikov product because of the regiochemical consequences of the product.

Explanation / Answer

(2) diastereomers

( Since, G and I are geometrical isomers. )

(3) diastereomers

( H and J are non-superimposable non-mirror images called diastereomers )

(4) True

(5) True

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