In this experiment we used ABCN as the initiator. There are other initiators tha

Question

In this experiment we used ABCN as the initiator. There are other initiators that could be used instead such as benzoyl peroxide (shown below). Give a curved arrow mechanism for how the reaction might be initiated with benzoyl peroxide using sulfuric chloride. Give the three steps of initiation.. In lecture you have learned about the free radical halogenations using either chlorine or bromine. You have also learned that bromine is more selective in its reaction than chlorine. Consider the compounds shown below and give the major product of reaction for each of these compounds with bromine (with hv). Rank the compounds in question 2 in order of increasing reactivity toward free radical bromination. Consider compound C from question 3. Give all possible products of free radical chlorination that are constitutional isomers. Circle the products that would exist as a pair of enantiomers.

Explanation / Answer

In this experiment we used ABCN as the initiator. There are other initiators tha

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