Academic Integrity: tutoring, explanations, and feedback — we don’t complete graded work or submit on a student’s behalf.

a) A + B -> 2C, delta H 1 2C ->A + B, delta H 2 = ? Delta H 2 =? b) A calorimete

ID: 917000 • Letter: A

Question

a) A + B -> 2C, delta H1

2C ->A + B, delta H2= ?

Delta H2=?

b) A calorimeter contains 25.0 mL of water at 12.5 degrees C. When 2.30 g of X (a substance with a molar mass of 42.0 g/mol) is added, it dissolves via the reaction: X(s)+H2O(l)->X(aq), and the temperature of the solution increases to 26.0 degrees C. Caluclate the enthalpy chance, delta H, for this reaction per mole of X. Assume that the specific heat of the resuting solution is equal to that of water [4.18 J/(g*degrees C)], that the desity of water is 1.00 g/mL, and that no heat is lost to the calorimeter itself, nor to the surroundings. Express answer in kJ/mol to 3 sig figs

Explanation / Answer

a) A + B -> 2C, delta H1

2C ->A + B, delta H2= -DH1

b) No of mol of X = 2.3/42 = 0.0547 mol

qreleased = m*s*DT

   mass of solution = 25*1+2.3 = 27.3 grams

specificheat of solution = 4.18 j/g.c

DT = 26-12.5 = 13.5 C

qreleased = 27.3*4.18*13.5 = 1540.54 joule.

DHrxn = -q/n = -1540.54/0.0547 = -28.16 kj/mol