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At 55.0 C, what is the vapor pressure of a solution prepared by dissolving 65.4

ID: 914315 • Letter: A

Question

At 55.0 C, what is the vapor pressure of a solution prepared by dissolving 65.4 g of LiF in 265 g of water? The vapor pressure of water at 55.0 C is 118 mmHg. Assume complete dissociation of the solute.

Submitted Answers

ANSWER 1: Deduction: -3%

42.7mmHg

ANSWER 2: Deduction: -3%

101mmHg

You have neglected the dissociation of LiF.

ANSWER 3:

100.741.mmHg

Use either an integer, decimal number, or scientific notation for the numeric portion of your answer. Do not use calculations or functions.

42.7mmHg

Explanation / Answer

Molar mass of water (H2O) = 18.015 gm/mol

Molar mass of Lithium Flouride (LiF) = 25.939 gm/mol

Number of moles of water = 265/18.015 = 14.71 moles

Number of moles of LiF = 65.4/25.939 = 2.521 * 2 (Li+ and F-) = 5.042 moles

Mole fraction of water = 14.71/(14.71+5.042) = 0.744

Pressure of Solution = molar fraction of H20 * pressure of H20

=> 0.7447 * 118 = 87.87 mm Hg

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