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The \"kinetic isotope effect\" is an expression used by organic chemists to desc

ID: 901300 • Letter: T

Question

The "kinetic isotope effect" is an expression used by organic chemists to describe the difference in reactivity between molecules that have deuterium (2H = D) compared to those with hydrogen (2H = H). The reactivity difference is believed to be due to the difference in bond strength between C-H and C-D. To a first approximation, the bond strength is equal to the Hooke's law constant for the bond. Assuming the vibrational frequency of C-H and C-D are equal, which bond is stronger? By what factor is it stronger? Why do you suppose the phenomenon is called "kinetic"?

Explanation / Answer

a. C-D is stronger by almost 80 times because of the highest weight of the atom which helps making strongest coavlent bond with C , thus stronger bond.

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