During denitrification, nitrate is reduced to nitrogen gas which can escape to t
ID: 894865 • Letter: D
Question
During denitrification, nitrate is reduced to nitrogen gas which can escape to the atmosphere. You are considering building a suspended solids reactor (activated sludge type) for denitrification of 30mg/l of NO-N. Nitrate is the nitrogen source for cell synthesis.
The energy equation for the reaction is:
6NO + 5CHOH ---> 3N + 5CO + 7HO + 6OH
The synthesis equation for the reaction is: NO + organic carbon ---> NO + organic carbon ---> N + CO + HO
A.) Assuming fs = 0.4, write a balanced equation for the overall reaction (normalize to one mole of NO).
B.) Estimate the quantity of acetic acid in mg/l requried for nitrate reduction (assume 1mg/l NO-N remains in the treated effluent).
Explanation / Answer
A.) Assuming fs = 0.4, write a balanced equation for the overall reaction is
NO + 5/6CHOH ---> 1/2N + 5/6CO + 7/6HO + OH (normalized to one mole of NO).
B.) To estimate the quantity of acetic acid in mg/l requried for nitrate reduction
usually 1mole of NO required 5/6 mole of acetic acid for reduction process.
i.e. 62 g of NO required 50 g of acetic acid for reduction process. Here, mass of acetic acid= 60 g/mol)
Now, assume 1mg/l NO required 0.8064 mg/l of acetic acid for reduction process.
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